NATIONAL REFRIGERANTS INC -- 1,1,1,2-TETRAFLUOROETHANE -- 6830-01-412-6362
===================== Product Identification ===================== Product ID:1,1,1,2-TETRAFLUOROETHANE MSDS Date:09/01/1995 FSC:6830 NIIN:01-412-6362 === Responsible Party === Company Name:NATIONAL REFRIGERANTS INC Address:89 WATER ST City:BRIDGETON State:NJ ZIP:08302-2545 Country:US Info Phone Num:609-455-4555 Emergency Phone Num:609-455-4555, CHEMTREC 800-424-9300 Preparer's Name:M. BEATTY/G. WILSON CAGE:4J994 === Contractor Identification === Company Name:NATIONAL REFRIGERANTS INC Address:661 KENYON AVE Box:City:BRIDGETON State:NJ ZIP:08302 Country:US Phone:800-262-0012/215-698-6620 CAGE:4J994 Company Name:NATIONAL REFRIGERANTS INC Address:11401 ROOSEVELT BLVD Box:City:PHILADELPHIA State:PA ZIP:19154 Country:US Phone:215-834-0200 CAGE:7Y146 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,1,2-TETRAFLUOROETHANE CAS:811-97-2 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT RELEVANT. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY TRACT, HEART. ACUTE- OVEREXPOSURE BY INHALATION TO VERY HIGH CONCENTRATIONS MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. LIQUID CONTACT/ESCAPING VAPOR S CAN CAUSE EYE AND SKIN FROSTBITE. INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:FROSTBITE, ASPHYXIATION, IRRITATION, HEART IRREGULARITIES, UNCONSCIOUSNESS, DEATH Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:FLUSH WITH WATER FOR 15 MINUTES. TREAT FOR FROSTBITE BY SLOWLY WARMING UP THE EXPOSED AREA. CALL PHYSICI AN. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. CALL A PHYSICIAN. ORAL:INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. NOTE TO PHYSICIAN:CATECHOLAMINES SHOULD NOT BE USED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:>1382F Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CYLINDERS MAY RUPTURE. DECOMPOSITION MAY OCCUR FORMING TOXIC AND/OR CORROSIVE GASES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA ESPECIALLY LOW OR ENCLOSED PLACES WHERE HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. SPILLS AND RELEASES MAY HAVE TO BE REPORTED TO AUTHORITIES. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED, DRY AREA AWAY FROM DIRECT SUNLIGHT, FLAMES AND INCOMPATIBLE MATERIALS. PROTECT CYLINDERS AGAINST PHYSICAL DAMAGE. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION. DO NOT STORE ABOVE 125F/52C. KEEP OUT OF REACH OF CHILDR EN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR IF A LARGE RELEASE OCCURS. Ventilation:NORMAL VENTILATION. LOCAL EXHAUST NEEDED WHEN LARGE AMOUNTS ARE RELEASED. Protective Gloves:LINED BUTYL WHEN HANDLING LIQUID Eye Protection:CHEMICAL SPLASH GOGGLES WHEN HANDLE LIQ. Other Protective Equipment:EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-16F,-27C Vapor Pres:4971 @ 77F Vapor Density:>1 Spec Gravity:1.20 (LIQUID) Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT (GAS) Solubility in Water:0.15% @ 77F Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS - FAINT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, MAGNESIUM, ZINC, BERYLLIUM, ETC. Stability Condition to Avoid:OPEN FLAME, HIGH TEMPERATURES, GLOWING METAL SURFACES, LIGHTED CIGARETTES Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN FLUORIDE AND POSSIBLY CARBONYL FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. CONTRACT WITH A PERMITTED WASTE DISPOSAL FACILITY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.