REAGENTS INC -- TRICHLOROETHYLENE -- 6810-00-285-4318
===================== Product Identification ===================== Product ID:TRICHLOROETHYLENE MSDS Date:08/30/2001 FSC:6810 NIIN:00-285-4318 Status Code:A === Responsible Party === Company Name:REAGENTS INC Address:4746 SWEDEN RD Box:240746 City:CHARLOTTE State:NC ZIP:28224 Country:US Info Phone Num:704-554-7474 Emergency Phone Num:704-554-7474 CAGE:0FK75 === Contractor Identification === Company Name:P AND D CREATIVE CO, INC Address:20140 SCHOLAR DR SUITE 211 Box:City:HAGERSTOWN State:MD ZIP:21742 Country:US Phone:301-797-3503 Contract Num:SP0450-01-M-ZG70 CAGE:1CVB1 Company Name:REAGENTS INC Address:4746 SWEDEN RD Box:240746 City:CHARLOTTE State:NC ZIP:28224 Country:US Phone:704-554-7474 CAGE:0FK75 ============= Composition/Information on Ingredients ============= Ingred Name:TRICHLOROETHYLENE CAS:79-01-6 RTECS #:KX4550000 = Wt:100. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:269 MG/M3;50 PPM ACGIH STEL:537 MG/M3;100 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50: 5650 MG/KG Reports of Carcinogenicity:NTP:YES IARC:YES Health Hazards Acute and Chronic:INHALATION: VAPORS CAN IRRITATE THE RESPIRATORY TRACT. CAUSES DEPRESSION OF THE CENTRAL NERVOUS SYSTEM INHALATION OF HIGH CONCENTRATIONS COULD CAUSE UNCONSCIOUSNESS, HEART EFFECTS, LIVER EFFECTS, KIDN EY EFFECTS, AND DEATH. INGESTION CAUSES IRRITATION TO GASTRONINTESTINAL TRACT. MAY ALSO CAUSE EFFECTS SIMILAR TO INHALATION. KIDNEY FAILURE CAN RESULT IN SEVERE CASES. ESTIMATED FATAL DOSE IS 3-5 ML/K G. SKIN CONTACT: CAUSE CAUSE IRRITATION, REDNESS AND PAIN. CAN CAUSE BLISTERING. EYE CONTACT: VAPORS CAN CAUSE SEVERE IRRITATION WITH REDNESS AND PAIN. CHRONIC: MAY CAUSE LIVER, KIDNEY, CNS & PERIPHE RAL NERVOUS SYSTEM EFFECTS. Explanation of Carcinogenicity:THIS MATERIAL IS A SUSPECT CARCINOGEN. NTP ANTICIPATED CARCINOGEN. IARC 2A CARCINOGEN. Effects of Overexposure:NHALATION:IRRITATE RESPIRATORY TRACT, DEPRESSION OF THE CENTRAL NERVOUS SYSTEM, VISUAL DISTURBANCES, MENTAL CONFUSION, INCOORDINATION, HEADACHE, NAUSEA, EUPHORIA & DIZZINESS. INHALATION COULD CAUSE UN CONSCIOUSNESS, HEART EFFECTS, LIVER EFFECTS, KIDNEY EFFECTS & DEATH. INGESTION: CAUSES IRRITATION TO GASTROINTESTINAL TRACT. MAY ALSO CAUSE EFFECTS SIMILAR TO INHALATION. MAY CAUSE COUGHING, ABDOMINAL PAIN, DIRRAHEA, DIZZINESS, PULMONARY EDEMA, UNCONSCIOUSNESS. KIDNEY FAILURE. SKIN: IRRITATION, REDNESS, PAIN, DEFATTING, ROUGH, DRY, RED SKIN. EYES: SEVERE IRRITATION, REDNESS, PAIN. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, CARDIVASCULAR DISORDERS, IMPAIRED LIVER OR KIDNEY OR RESPIRATORY FUNCTIONS, OR CENTRAL OR PERIPHERAL NERVOUS SYSTEM. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICAN. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL P ERSONNEL. NOTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN. SKIN CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES . GET MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. ===================== Fire Fighting Measures ===================== Lower Limits:8 Upper Limits:12.5 Extinguishing Media:USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL. IF SUBSTANCE DOES IGNITE, USE CO2, DRY CHEMICAL OR FOAM. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. COMBUSTION BY-PRODUCTS INCLUDE PH OSGENE & HYDROGEN CHLORIDE GASES. STRUCTURAL FIREFIGHTERS CLOTHING PROVIDES ONLY LIMITED PROTECTION. Unusual Fire/Explosion Hazard:A STRONG IGNITION SOURCE E.G. A WELDING TORCH, CAN PRODUCE IGNITION. SEALED CONTAINERS MAY RUPTURE WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. REMOVE ALL SOURCES OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN SECTION 8. ISOLATE HAZARD AREA. KEEP UNNCESSARY AND UNPROTECTED PERSONNE L FROM ENTERING. CONTAIN AND RECOVER LIQUID WHEN POSSIBLE. USE NON-SPARKING TOOLS AND EQUIPMENT. COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR ABSORB WITH AN INERT MATERIAL (E.G., VERMICULITE, DRY Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM ANY SOURCE OF HEAT OR IGNITION. ISOLATE FROM INCOMPIBLE SUBSTANCES. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID). Other Precautions:OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED AND ENGINEERING CONTROLS ARE NOT FEASIBLE, WEAR A SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD, OR FULL-FACEPIECE SELF-CONTAINED BREATHING APPARATUS. BREATH ING AIR QUALITY MUST MEET THE REQUIREMENTS OF THE OSHA RESPIRATORY PROTECTION STANDARD (29CFR1910.134). THIS SUBSTANCE HAS POOR WARNING PROPERTIES. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEES BELOW THE AIRBORNE EXPOSURE LIMITS. LOCAL EXHAUST VENTILATION IS GENERALLY PREFERRED Protective Gloves:WEAR IMPERVIOUS GLOVES Eye Protection:USE CHEMICAL SAFETY GOGGLES AND/OR A FULL FACE SHIELD WHERE SPLASHING IS Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE TO PREVENT SKIN CONTACT. NEOPRENE IS A RECOMMENDED MATERIAL FOR PERSONAL PROTECTIVE EQUIPMENT. Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. THROUGHLY CLEAN SHOES BEFORE REUSE. Supplemental Safety and Health NOTE TO PHYSICIAN: DO NOT ADMINISTER ADRENALINE OR EPHINEPHRINE TO A VICTIM OF CHLORINATED SOLVENT POISONING. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:=87.2C, 189.F Melt/Freeze Pt:=-72.6C, -99.F Vapor Pres:57.8 @ 20C (68F) Vapor Density:4.5 Spec Gravity:1.47@20C/4C Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:INSOLUBLE IN WATER. Appearance and Odor:CLEAR, COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG CAUSTICS AND ALKALIS, STRONG OXIDIZERS, CHEMICALLY ACTIVE METALS, SUCH AS BARIUM, LITHIUM, SODIUM, MAGNESIUM, TITANIUM AND BERYLLIUM, LIQUID OXYGEN. Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS OF USE & STORAGE. WLL SLOWLY DECOMPOSE TO HYDROCHLORIC ACID WHEN EXPOSED TO LIGHT & MOISTURE. Hazardous Decomposition Products:MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE AND PHOSGENE WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TRICHLOROETHYLENE: ORAL RAT LD50: 5650 MG/KG; INVESTIGATED AS A TUMORIGEN, MUTAGEN, REPRODUCTIVE EFFECTOR. REPRODUCTIVE TOXICITY: THIS MATERIAL HAS BEEN LINKED TO MUTAGENIC EFFECTS IN HUMANS. ===================== Ecological Information ===================== Ecological:WHEN RELEASED INTO THE SOIL, THIS MATERIAL MAY LEACH INTO GROUNDWATER. WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE. WHEN RELEASED TO WATER, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE. THIS MATERIAL HAS AN EXPERIMENTALLY-DETERMINED BIOCONCENTRATION FACTOR (BCF) OF LESS THAN 100. THIS MATERIAL IS NOT EXPECTED TO SIGNIFIGANTLY BIOACCUMULATE. (SEE OTHER INFORMATION) . ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE AND SENT TO A RCRA APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY. PROCESSING, USE OR CONTAM INATION OF THIS PRODUCT MAY CHANGE THE WAST MANAGEMENT OPTIONS. STATE AND LOCAL DISPOSAL REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOMESTIC (LAND, DOT): PROPER SHIPPING NAME: TRICHLOROETHYLENE. HAZARD CLASS: 6.1. UN/NA: UN1710. PACKING GROUP: III. INTERNATIONAL (WATER, IMO): PROPER SHIPPING NAME: TRICHLOROETHYLENE. HAZARD CLASS: 6.1. UN/NA: UN1710. PACKING GROUP: III. INTERNATIONAL (AIR, ICAO): PROPER SHIPPING NAME: TRICHLOROETHYLENE. HAZARD CLASS: 6.1. UN/NA: UN1710. PACKING GROUP: III. ===================== Regulatory Information ===================== SARA Title III Information:TRICHLOROETHYLENE (CAS# 79-01-6): SARA 302 RQ-NO, SARA 302 TPQ-NO, SARA 313 LIST-YES, SARA 313 CATG-NO, CERCLA-100 (LBS), SARA 311/312-ACUTE, CHRONIC. Federal Regulatory Information:RCRA 261.33-U228, TSCA 8(D)-NO, CHEMICAL WARFARE CONVENTION-NO, TSCA 12(B)-NO, CDTA-NO. State Regulatory Information:WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.