MALLINCKRODT INC SCIENCE PRODUCTS DIV -- SALICYLIC ACID -- 6505-01-188-5384
===================== Product Identification ===================== Product ID:SALICYLIC ACID MSDS Date:07/13/1987 FSC:6505 NIIN:01-188-5384 === Responsible Party === Company Name:MALLINCKRODT INC SCIENCE PRODUCTS DIV Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:606-987-7000, 314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:SALICYLIC ACID CAS:69-72-7 RTECS #:VO0525000 Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 891 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. SKIN: MILD IRRITATION, RASH. ABSORPTION MAY PRODUCE SYMPTOMS PARALLELING INGESTION EXPOSURE. INHALATION: DUST MAY CAUSE IRRITATION. INGESTION: LARGE AMOUNTS CAN CAUSE "SALICYL ISM", ABDOMINAL PAIN, VOMITING, MENTAL DISTURBANCES, CNS DISTURBANCES, CONVULSIONS, AFFECT KIDNEY AND PANCREAS, DEATH. Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, RASH, AND SYMPTOMS SIMILAR TO THOSE FROM INGESTION. INHALATION: IRRITATION, INGESTION: ABDOMINAL PAIN, VOMITING, MENTAL DISTURBANCES, CNS DISTURBANCES, CONVULSIONS, AFFECT KIDNEYS AND PANCREAS. FATALITIES RESULTING FROM RESPIRATORY OR CARDIOVASCULAR FAILURE ARE KNOWN. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, RESPIRATORY TRACT, OR IMPAIRED KIDNEY FUNCTION MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. IF IRRITATION PERSISTS , GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: GIVE TWO GLASSES OF WATER OR MILK. INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, CARBON DIOXIDE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SCBA WITH FULL FACEPIECE OPERATED IN PRESS. MODE. FIRE IS POSSIBLE AT ELEVATED TEMP. AND WITH IGNITION SOURCE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSIVE HAZARD. SUBLIMES AT 169F. DECOMPOSES ON HEATING AT ATMOSPHERIC PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL MAY REQUIRE RESPIRATORY PROTECTION FROM DUST. SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUM OR WET SWEEPING MAY BE USED TO AVOID DUS T DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN DARK,COOL,DRY,VENTILATED AREA IN CLOSED CONTAINER AWAY FROM SOURCES OF HEAT OR IGNITION, AND OXIDIZING AGENTS. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:AVOID SKIN AND EYE CONTACT. AVOID INHALATION OF DUSTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO DUST IS APPARENT, A DUST/MIST RESPIRATOR MAY BE WORN. FOR EMERGENCIES, A SELF-CONTAINED BREATHING APPARATUS MAY BE NECESSARY. Ventilation:USE LOCAL EXHAUST TO CAPTURE CONTAMINANTS AT ITS SOURCE TO PREVENT DISPERSION OF CONTAMINANT INTO THE WORKROOM AIR. Protective Gloves:WEAR PROTECTIVE GLOVES. Eye Protection:SAFETY GOGGLES. Other Protective Equipment:DO NOT WEAR CONTACT LENSES. PROVIDE AN EYE WASH SATION AND SAFETY SHOWER IN WORK AREA. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:412F,211C Melt/Freeze Pt:M.P/F.P Text:315F,157C Decomp Temp:Decomp Text:ON HEATING Vapor Pres:1.0 @ 237F Spec Gravity:1.44 Evaporation Rate & Reference:SUBLIMES AT 168F. Solubility in Water:1.8 GM/100 ML WATER Appearance and Odor:FINE, WHITE CRYSTALS. ODORLESS OR SLIGHT PHENOLIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES IRON SALTS, LEAD ACETATE, IODINE, NITROUS ETHER. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. DARKENS ON EXPOSURE TO AIR OR LIGHT. Hazardous Decomposition Products:TOXIC GASES RELEASED IN A FIRE. WHEN RAPIDLY HEATED AT ATMOS. PRESS. IT DECOMPOSES INTO PHENOL AND CARBON DIOXIDE. Conditions to Avoid Polymerization:THIS SUBSTANCE DOES NOT POLYMERIZE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.